WOW. This IS interesting. I was recently hired into the architecture group of the company I am working for now. This was my first problem, and I had to think long and hard about it.
Six Sigma is defect based, and describes any defect as "anything that would lead to customer dissatisfaction"
We expanded it to three areas of quality:
Quality of Conformance (does the system function in the way we understand the requirements?)
Quality of Features ( do the features make sense?)
Lack of Defects (crashing etc)
This is working so far. Thanks!